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Octane number, also called octane rating, is a measure of a fuel's ability to resist "knocking" or "pinging" during combustion in an internal combustion engine, particularly in gasoline engines.  Knocking occurs when the air-fuel mixture in the engine's cylinder ignites prematurely or unevenly, which can lead to inefficient combustion and potential engine damage.  The octane number is determined by comparing a fuel's performance to a mixture of two hydrocarbons: iso-octane (which has excellent resistance to knocking and is assigned an octane number of 100) and n-heptane (which knocks easily and is assigned an octane number of 0).
 
Octane Ratings (U.S.)
 
Regular Gasoline (87)  -  This is the standard fuel for most everyday vehicles in the U.S.  RON is typically around 91–92, and MON around 82–83.
Mid-grade Gasoline (89)  -  A step up from regular, used in some vehicles that benefit from slightly higher knock resistance.  RON might be around 93–94, MON around 84–85.
Premium Gasoline (91-94)  -  Common ratings include 91, 92, or 93 (varies by region and brand).  Used in high-performance or luxury cars with higher compression engines.
High-Octane Fuels (100 or Higher)  -  Specialty fuels like 100-octane gasoline are used in aviation, racing, or extreme performance vehicles.  Aviation gasoline (avgas) often has ratings like 100LL (low lead), with a RON around 100–104.  Racing fuels can go even higher, like 110 or 120, depending on additives and formulation.
 
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